In This Issue:

The Caliper V15 #1 Cover
CBL™ News
Water-Quality Studies
Science Humor
Innovative Uses
Bits and Bytes
Workshops & Contests
What's New

Go to past issues of
The Caliper

Return to
Vernier Home Page

The Caliper
A Publication for Users of Vernier Products
Volume 15, Number 1Spring 1998

Using Vernier Sensors for Water-Quality Studies

by Dan Holmquist and Scott Holman

With the introduction of our new Vernier Ion-Selective Electrodes, we decided it was time to do a trial water quality study in the greater Portland, Oregon area. Our choice was the Tualatin River, a medium-sized river that flows about 100 miles from the Coastal Range west of Portland to its eventual confluence with the Willamette River near the center of Portland. We collected water samples at four locations on April 24th at the following locations:

  • Site 1: After the river flows from the heavily-forested Coastal Range
  • Site 2: After the river meanders through agricultural land for 15 miles
  • Site 3: After the river has gone through more agricultural land and residential suburbs
  • Site 4: After the river flows several more miles through populated suburbs of Portland
Measurements were made at each site using a portable CBL™ and TI Graphing Calculator. We also made use of a PC laptop computer using a Serial Box Interface (with a Rechargeable Battery Pack). We made other measurements soon after returning from the trip (nitrate, calcium, chloride, ammonium, conductivity). Even though the levels of several of these ions in the Tualatin River water were as low as 1 mg/L (1 part per million), the new ion-selective electrodes provided very stable, reproducible results. Here is a summary of some of the measurements:

  • As expected, temperature increased from site 1-4 (9.5, 12.1, 13.3, and 13.3°C).
  • The pH values, measured using a Vernier pH System, hovered very close to a value of 7, which is typical for western Oregon water (7.12, 6.99, 7.01, and 7.04).
  • The Conductivity Probe revealed that the level of total dissolved solids (TDS) increased significantly from site 1-4 (32.2, 41.1, 56.0, and 64.6 mg/L TDS, respectively).
Since the conductivity tests showed a steady increase in ion concentration of the stream, we were quite curious to see the results of our tests using our ion-selective electrodes. Because a significant part of total dissolved solids is usually due to either hard-water ions (e.g., Ca2+, Mg2+, Fe3+, or HCO3-), or salts dissolved from the stream bed (e.g., Na+ or Cl-), we made measurements of the Ca2+ and Cl- concentrations (using the Vernier Calcium ISE and Chloride ISE). Here are the results:



Calcium, Ca2+ Chloride, Cl-


The results indicated a gradual increase in the Ca2+ and Cl- ion concentrations throughout the four sites. As is typical for western Oregon water, water hardness is very low; the highest Ca2+ concentration (17.3 mg/L) would correspond to a Calcium Water Hardness value of 44.0 mg/L, a value considered "very soft water." The highest chloride concentration (8.1 mg/L) is far below the EPA chloride drinking water standard of 250 mg/L.

Because the Tualatin River flows through agricultural areas between sites 1 and 3, and flows through populated areas (between sites 3 and 4), we thought it might be interesting to see how nitrate (NO3-) and ammonium (NH4+) levels were affected. Here are the results of each of these tests:



Ammonium, NH4+ Nitrate, NO3-


There is a noticeable increase in both nitrate and ammonium ion concentrations. These may be due to runoff of fertilizers from farm fields between sites 1 and 3. Stream flow drops significantly after site 1, so decomposition of biological matter may contribute to the increased levels of nitrate ions. Water with nitrate levels less than 1 mg/L are generally considered to be "unpolluted," while levels higher than 10 mg/L are unsafe for drinking water. The peak nitrate level of 2.53 mg/L at site 4 is moderately high.

We also made dissolved oxygen measurements using the Vernier Dissolved Oxygen Probe. This small decrease in dissolved oxygen concentration shown below may be due to an increase in biological decomposition in the stream.


Dissolved Oxygen Concentration

The purpose of this article is to show how easily data can be collected using a variety of Vernier sensors and portable data acquisition systems. Your students can experience the same kind of excitement we did while investigating a local lake or stream. The following sensors were used in our experiments:

Sensor Order Code Price:

ISE AmplifierISE-DIN$39
Ammonium ISENH4-ISE$149
Calcium ISECA-ISE$149
Chloride ISECL-ISE$149
Nitrate ISENO3-ISE$149
pH SystemPH-DIN$72
Conductivity ProbeCON-DIN$79
Extra Long Temperature ProbeTPL-DIN$68
Dissolved Oxygen ProbeDO-DIN$189

Home | Products | Technical Support | Ordering


Vernier Software & Technology
letter info@vernier.com 13979 SW Millikan Way
Beaverton, OR 97005-2886
Ph. (503) 277-2299 Fax (503) 277-2440