Standardizing a Solution of Sodium Hydroxide
Recommended for grades 9–12.

Introduction
It is often necessary to test a solution of unknown concentration with a solution of a known, precise concentration. The process of determining the unknown’s concentration is called standardization.
Solutions of sodium hydroxide are virtually impossible to prepare to a precise molar concentration because the substance is hygroscopic. In fact, solid NaOH absorbs so much moisture from the air that a measured sample of the compound is never 100% NaOH. On the other hand, the acid salt potassium hydrogen phthalate, KHC8H4O4, can be measured out in precise mass amounts. It reacts with NaOH in a simple 1:1 stoichiometric ratio, thus making it an ideal substance to use to standardize a solution of NaOH.
Objectives
In this experiment, you will
- Prepare an aqueous solution of sodium hydroxide to a target molar concentration.
- Determine the concentration of your NaOH solution by titrating it with a solution of potassium hydrogen phthalate, abbreviated KHP, with an exact molar concentration.
Sensors and Equipment
This experiment requires each of the following Vernier sensors and equipment (unless otherwise noted):


Drop Counter (optional)
Additional Requirements
You may also need an interface and software for data collection. What do I need for data collection?
Download Experiment Preview
The student-version preview includes:
- Step-by-step instructions for computer-based data collection
- List of materials and equipment
Note: The experiment preview of the computer edition does not include essential teacher information, safety tips, or sample data. Instructions for Logger Pro and other software (such as LabQuest App or TI handheld software, where available) are on the CD that accompanies the book. We strongly recommend that you purchase the book before performing experiments.
Standards Correlations
See all standards correlations for Advanced Chemistry with Vernier »
